HazMat Tool — substance information

Lithium nitrate

HMT May 2026

UN / ID: UN 2722
Hazard class: 5.1
Packing group: III
ERG guide: ERG 140
Special provisions: SP A1, SP IB8, SP IP3, SP T1, SP TP33
Source: 49 CFR §172 (2026/05)

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Lithium nitrate

Lithium nitrate is an inorganic compound with the formula LiNO3. It is the lithium salt of nitric acid (an alkali metal nitrate). The salt is deliquescent, absorbing water to form the hydrated form, lithium nitrate trihydrate. Its eutectics are of interest for heat transfer fluids. It is made by treating lithium carbonate or lithium hydroxide with nitric acid. Wikipedia

Emergency Response Guide No. 140

Hazardous Materials Table

Source: 49 CFR §172 (2026/05)

(3) Hazard Class

5.1
Oxidizers

(4) Identification number

UN 2722

(5) Packing Group

III

(6) Labels

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

Single packagings are not permitted on passenger aircraft.

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IB8

Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2 ); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2 and 31HZ1); Fiberboard (11G); Wooden (11C, 11D and 11F); Flexible (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2).

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IP3

Flexible IBCs must be sift-proof and water-resistant or must be fitted with a sift-proof and water-resistant liner.

Browse special provision IP3

Minimum test pressure (bar)	1.5
Minimum shell thickness	§ 178.274(d)(2)
Pressure-relief requirements	Normal
Bottom opening requirements	§ 178.275(d)(2)

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TP33

The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point which are cooled and transported as a solid mass. Solid substances transported or offered for transport above their melting point are authorized for transportation in portable tanks conforming to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II, unless a tank with more stringent requirements for minimum shell thickness, maximum allowable working pressure, pressure-relief devices or bottom outlets are assigned in which case the more stringent tank instruction and special provisions shall apply. Filling limits must be in accordance with portable tank special provision TP3. Solids meeting the definition of an elevated temperature material must be transported in accordance with the applicable requirements of this subchapter.

Browse special provision TP33

(8) Packing Authorizations (§173.***)

(8A) Exceptions	152	see 49 CFR §173.152
(8B) Non-bulk	213	see 49 CFR §173.213
(8C) Bulk	240	see 49 CFR §173.240

(9) Quantity Limits

(9A) Passenger aircraft/rail	25 kg
(9B) Cargo aircraft only	100 kg

(10) Vessel stowage

(10A) Location	A Stowage category “A” means the material may be stowed “on deck” or “under deck” on a cargo vessel or on a passenger vessel. Source: 49 CFR §172.101(k)
(10B) Other	n/a

Segregation chart for load, transport, and storage

This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.

Hazard class	8	7	6.1	5.2	5.1	4.3	4.2	4.1	3	2.3B	2.3A	2.2	2.1	1.6	1.5	1.4	1.3	1.1/1.2
1.1/1.2
1.3
1.4
1.5
1.6
2.1
2.2
2.3A
2.3B
3
4.1
4.2
4.3
5.1
5.2
6.1
7
8

	Must not be loaded, transported, or stored together in the same vehicle or facility.
	May be loaded, transported, or stored together.
	May be loaded, transported, or stored together only with restrictions.

Similar substances

UN / ID	Proper shipping name	Hazard class
UN 3536	Lithium batteries installed in cargo transport unit lithium ion batteries or lithium metal batteries	9
UN 3481	Lithium ion batteries contained in equipment including lithium ion polymer batteries	9
UN 3481	Lithium ion batteries packed with equipment including lithium ion polymer batteries	9
UN 3091	Lithium metal batteries contained in equipment including lithium alloy batteries	9
UN 3091	Lithium metal batteries packed with equipment including lithium alloy batteries	9
UN 3480	Lithium ion batteries including lithium ion polymer batteries	9
UN 1471	Lithium hypochlorite, dry or Lithium hypochlorite mixture	5.1
UN 3090	Lithium metal batteries including lithium alloy batteries	9
UN 1411	Lithium aluminum hydride, ethereal	4.3
UN 2805	Lithium hydride, fused solid	4.3
UN 1410	Lithium aluminum hydride	4.3
UN 2679	Lithium hydroxide, solution	8