HazMat Tool — substance information

3-Methylbutan-2-one

HMT May 2026

UN / ID: UN 2397
Hazard class: 3
Packing group: II
ERG guide: ERG 127
Special provisions: SP IB2, SP T4, SP TP1
Source: 49 CFR §172 (2026/05)

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3-Methylbutan-2-one

3-Methyl-2-butanone (methyl isopropyl ketone, MIPK) is a ketone and solvent of minor importance. It is comparable to MEK (Methyl ethyl ketone), but has a lower solvency and is more expensive. Wikipedia

Emergency Response Guide No. 127

Hazardous Materials Table

Source: 49 CFR §172 (2026/05)

(3) Hazard Class

3
Flammable liquids

(4) Identification number

UN 2397

(5) Packing Group

(6) Labels

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

IB2

_{Authorized IBCs:} Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1).
_{Additional Requirement:} Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized.

Browse special provision IB2

Minimum test pressure (bar)	2.65
Minimum shell thickness	§ 178.274(d)(2)
Pressure-relief requirements	Normal
Bottom opening requirements	§ 178.275(d)(3)

Browse special provision T4

TP1

The maximum degree of filling must not exceed the degree of filling determined by the following:
TP1

Where:
t_r is the maximum mean bulk temperature during transport, and t_f is the temperature in degrees celsius of the liquid during filling.

Browse special provision TP1

(8) Packing Authorizations (§173.***)

(8A) Exceptions	150	see 49 CFR §173.150
(8B) Non-bulk	202	see 49 CFR §173.202
(8C) Bulk	242	see 49 CFR §173.242

(9) Quantity Limits

(9A) Passenger aircraft/rail	5 L
(9B) Cargo aircraft only	60 L

(10) Vessel stowage

(10A) Location	B Stowage category “B” means (i) The material may be stowed “on deck” or “under deck” on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and (ii) “On deck only” on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded. Source: 49 CFR §172.101(k)
(10B) Other	n/a

Segregation chart for load, transport, and storage

This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.

Hazard class	8	7	6.1	5.2	5.1	4.3	4.2	4.1	3	2.3B	2.3A	2.2	2.1	1.6	1.5	1.4	1.3	1.1/1.2
1.1/1.2
1.3
1.4
1.5
1.6
2.1
2.2
2.3A
2.3B
3
4.1
4.2
4.3
5.1
5.2
6.1
7
8

	Must not be loaded, transported, or stored together in the same vehicle or facility.
	May be loaded, transported, or stored together.
	May be loaded, transported, or stored together only with restrictions.

Similar substances

UN / ID	Proper shipping name	Hazard class
UN 2341	1-Bromo-3-methylbutane	3
UN 2457	2,3-Dimethylbutane	3
UN 3371	2-Methylbutanal	3