HazMat Tool — substance information

Sodium cyanide solution

HMT May 2026

UN / ID: UN 3414
Hazard class: 6.1
Packing group: I (multiple — see tabs)
ERG guide: ERG 157
Special provisions: SP B69, SP B77, SP N74, SP N75, SP T14, SP TP2, SP TP13, SP W31
Source: 49 CFR §172 (2026/05)

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Sodium cyanide solution

Substance Data

Source: PubChem (HSDB, 10.12.2019)

CAS-Number

143-33-9

Flash Point

n/a

Boiling Point

n/a

Emergency Response Guide No. 157

Hazardous Materials Table

Source: 49 CFR §172 (2026/05)

Packing group I
Packing group II
Packing group III

(3) Hazard Class

6.1
Poisonous Material

(7) Special Provisions (§172.102)

×Note:
Special provisions may be very complex. The extracts are taken from 49 CFR §172.102. Please be careful with the information, as necessary, additional conditions may be applied that are not written here. Please check the original source and report bugs.

B69

Dry sodium cyanide or potassium cyanide may be shipped in the following sift-proof and weather-resistant packagings: metal covered hopper cars, covered motor vehicles, portable tanks, or non-specification bins.

Browse special provision B69

B77

Other packaging are authorized when approved by the Associate Administrator.

Browse special provision B77

N74

Packages consisting of tightly closed inner containers of glass, earthenware, metal or polyethylene, capacity not over 0.5 kg (1.1 pounds) securely cushioned and packed in outer wooden barrels or wooden or fiberboard boxes, not over 15 kg (33 pounds) net weight, are authorized and need not conform to the requirements of part 178 of this subchapter.

Browse special provision N74

N75

Packages consisting of tightly closed inner packagings of glass, earthenware or metal, securely cushioned and packed in outer wooden barrels or wooden or fiberboard boxes, capacity not over 2.5 kg (5.5 pounds) net weight, are authorized and need not conform to the requirements of part 178 of this subchapter.

Browse special provision N75

T14

Minimum test pressure (bar)	6
Minimum shell thickness	6 mm
Pressure-relief requirements	§ 178.275(g)(3)
Bottom opening requirements	Prohibited

Browse special provision T14

TP2

a. The maximum degree of filling must not exceed the degree of filling determined by the following:
TP2a

Where:
t_r is the maximum mean bulk temperature during transport,
t_f is the temperature in degrees celsius of the liquid during filling, and
α is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (t_f) and the maximum mean bulk temperature during transportation (t_r) both in degrees celsius.
b. For liquids transported under ambient conditions α may be calculated using the formula:
TP2b

Where:
d₁₅ and d₅₀ are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively.

Browse special provision TP2

TP13

Self-contained breathing apparatus must be provided when this hazardous material is transported by sea.

Browse special provision TP13

W31

Non-bulk packagings must be hermetically sealed.

Browse special provision W31

(8) Packing Authorizations (§173.***)

(8A) Exceptions	None
(8B) Non-bulk	201	see 49 CFR §173.201
(8C) Bulk	243	see 49 CFR §173.243

(9) Quantity Limits

(9A) Passenger aircraft/rail	1 L
(9B) Cargo aircraft only	30 L

(10) Vessel stowage

(10A) Location

Stowage category “B” means

(i) The material may be stowed “on deck” or “under deck” on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and
(ii) “On deck only” on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded.

Source: 49 CFR §172.101(k)

(10B) Other

52	see 49 CFR §176.84

Source: 49 CFR §176.84

(3) Hazard Class

6.1
Poisonous Material

(4) Identification number

UN 3414

(5) Packing Group

Comparison View of PG

(6) Labels

(7) Special Provisions (§172.102)

B69

Browse special provision B69

B77

Other packaging are authorized when approved by the Associate Administrator.

Browse special provision B77

IB2

Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1).
Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized.

Browse special provision IB2

N74

Browse special provision N74

N75

Browse special provision N75

T11

Minimum test pressure (bar)	6
Minimum shell thickness	§ 178.274(d)(2)
Pressure-relief requirements	Normal
Bottom opening requirements	§ 178.275(d)(3)

Browse special provision T11

TP2

a. The maximum degree of filling must not exceed the degree of filling determined by the following:
TP2a

Where:
d₁₅ and d₅₀ are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively.

Browse special provision TP2

TP13

Self-contained breathing apparatus must be provided when this hazardous material is transported by sea.

Browse special provision TP13

TP27

A portable tank having a minimum test pressure of 4 bar (400 kPa) may be used provided the calculated test pressure is 4 bar or less based on the MAWP of the hazardous material, as defined in §178.275, where the test pressure is 1.5 times the MAWP.

Browse special provision TP27

W31

Non-bulk packagings must be hermetically sealed.

Browse special provision W31

(8) Packing Authorizations (§173.***)

(8A) Exceptions	153	see 49 CFR §173.153
(8B) Non-bulk	202	see 49 CFR §173.202
(8C) Bulk	243	see 49 CFR §173.243

(9) Quantity Limits

(9A) Passenger aircraft/rail	5 L
(9B) Cargo aircraft only	60 L

(10) Vessel stowage

(10A) Location

Stowage category “B” means

(i) The material may be stowed “on deck” or “under deck” on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and
(ii) “On deck only” on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded.

Source: 49 CFR §172.101(k)

(10B) Other

52	see 49 CFR §176.84

Source: 49 CFR §176.84

(3) Hazard Class

6.1
Poisonous Material

(4) Identification number

UN 3414

(5) Packing Group

III

Comparison View of PG

(6) Labels

(7) Special Provisions (§172.102)

B69

Browse special provision B69

B77

Other packaging are authorized when approved by the Associate Administrator.

Browse special provision B77

IB3

Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1 and 31HA2, 31HB2, 31HN2, 31HD2 and 31HH2).
Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 °C (1.1 bar at 122 °F), or 130 kPa at 55 °C (1.3 bar at 131 °F) are authorized, except for UN2672 (also see special provision IP8 in Table 2 for UN2672).

Browse special provision IB3

N74

Browse special provision N74

N75

Browse special provision N75

Minimum test pressure (bar)	4
Minimum shell thickness	§ 178.274(d)(2)
Pressure-relief requirements	Normal
Bottom opening requirements	§ 178.275(d)(3)

Browse special provision T7

TP2

a. The maximum degree of filling must not exceed the degree of filling determined by the following:
TP2a

Where:
d₁₅ and d₅₀ are the densities (in units of mass per unit volume) of the liquid at 15 °C (59 °F) and 50 °C (122 °F), respectively.

Browse special provision TP2

TP13

Self-contained breathing apparatus must be provided when this hazardous material is transported by sea.

Browse special provision TP13

TP28

A portable tank having a minimum test pressure of 2.65 bar (265 kPa) may be used provided the calculated test pressure is 2.65 bar or less based on the MAWP of the hazardous material, as defined in §178.275, where the test pressure is 1.5 times the MAWP.

Browse special provision TP28

W31

Non-bulk packagings must be hermetically sealed.

Browse special provision W31

(8) Packing Authorizations (§173.***)

(8A) Exceptions	153	see 49 CFR §173.153
(8B) Non-bulk	203	see 49 CFR §173.203
(8C) Bulk	241	see 49 CFR §173.241

(9) Quantity Limits

(9A) Passenger aircraft/rail	60 L
(9B) Cargo aircraft only	220 L

(10) Vessel stowage

(10A) Location

Stowage category “A” means the material may be stowed “on deck” or “under deck” on a cargo vessel or on a passenger vessel.

Source: 49 CFR §172.101(k)

(10B) Other

52	see 49 CFR §176.84

Source: 49 CFR §176.84

Packing group comparison

Multiple packing groups apply to this entry. See assignment criteria in 49 CFR §173 Subpart D. Details are in the tabs above; differences are highlighted.

	PG I	PG II	PG III
1
2	Sodium cyanide solution	Sodium cyanide solution	Sodium cyanide solution
3	6.1	6.1	6.1
4	UN 3414	UN 3414	UN 3414
5	I	II	III
6	6.1	6.1	6.1
7	B69, B77, N74, N75, T14, TP2, TP13, W31	B69, B77, IB2, N74, N75, T11, TP2, TP13, TP27, W31	B69, B77, IB3, N74, N75, T7, TP2, TP13, TP28, W31
8A	None	153	153
8B	201	202	203
8C	243	243	241
9A	1 L	5 L	60 L
9B	30 L	60 L	220 L
10A	B	B	A
10B	52	52	52

Segregation chart for load, transport, and storage

This chart shows whether loading, transport, or storage with other hazard classes is permitted, prohibited, or restricted. Based on 49 CFR §177.848.

Note: The HMR prohibit only those Division 6.1 liquids that meet the definition of a Packing Group (PG) I and Hazard Zone A. See special provision 1 and PHMSA Interpretation #09-0252.

Packages with POISON or POISON INHALATION HAZARD labels, or a POISON label displaying “PG III,” or “PG III” marked next to a POISON label may not be transported with foodstuffs, feed or any other edible material, intended for humans or animals. For exceptions see 49 CFR §177.841(e).

Scope & sources (important)Click to show CFR references

This check evaluates segregation per 49 CFR §177.848. Additional loading/unloading and handling requirements may still apply; see 49 CFR §177 Subpart B (Loading and Unloading):

§177.834 - General requirements
§177.835 - Class 1 materials
§177.837 - Class 3 materials
§177.838 - Class 4 (flammable solid) materials, Class 5 (oxidizing) materials, and Division 4.2 (pyroforic liquid) materials
§177.839 - Class 8 (corrosive) materials
§177.840 - Class 2 (gases) materials
§177.841 - Division 6.1 and Division 2.3 materials
§177.842 - Class 7 (radioactive) material
§177.843 - Contamination of vehicles

Similar substances

UN / ID	Proper shipping name	Hazard class
UN 1613	Hydrocyanic acid, aqueous solutions or Hydrogen cyanide, aqueous solutions with not more than 20 percent hydrogen cyanide	6.1
UN 1614	Hydrogen cyanide, stabilized, with less than 3 percent water and absorbed in a porous inert material	6.1
UN 3294	Hydrogen cyanide, solution in alcohol with not more than 45 percent hydrogen cyanide	6.1
NA 1613	Hydrocyanic acid, aqueous solutions with less than 5 percent hydrogen cyanide	6.1
UN 1051	Hydrogen cyanide, stabilized with less than 3 percent water	6.1
UN 1588	Cyanides, inorganic, solid, n.o.s.	6.1
UN 1694	Bromobenzyl cyanides, liquid	6.1
UN 3449	Bromobenzyl cyanides, solid	6.1
UN 1642	Mercury oxycyanide, desensitized	6.1
UN 1680	Potassium cyanide, solid	6.1
UN 1935	Cyanide solutions, n.o.s.	6.1
UN 1626	Mercuric potassium cyanide	6.1
	Mercury oxycyanide	Forbidden
UN 1679	Potassium cuprocyanide	6.1
UN 2316	Sodium cuprocyanide, solid	6.1